Download C-H Bond Activation and Catalytic Functionalization I by Pierre H. Dixneuf, Henri Doucet PDF

By Pierre H. Dixneuf, Henri Doucet

The sequence subject matters in Organometallic Chemistry provides severe overviews of analysis ends up in organometallic chemistry. As our knowing of organometallic constitution, homes and mechanisms raises, new methods are opened for the layout of organometallic compounds and reactions adapted to the desires of such various parts as natural synthesis, scientific examine, biology and fabrics technological know-how. hence the scope of insurance incorporates a extensive diversity of themes of natural and utilized organometallic chemistry, the place new breakthroughs are being completed which are of value to a bigger medical viewers. the person volumes of issues in Organometallic Chemistry are thematic. overview articles are regularly invited through the amount editors. All chapters from subject matters in Organometallic Chemistry are released OnlineFirst with someone DOI. In references, subject matters in Organometallic Chemistry is abbreviated as best Organomet Chem and stated as a journal.

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2 Intramolecular C–H Activation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Activation of C(sp2)–H Bonds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Activation of C(sp3)–H Bonds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Intermolecular C–H Activation . . . . . . . . . . . . . . . . . . . . . .

10 New Trends and Perspectives Extraordinary advances achieved in the C–H activation field benefiting from the [Cp*M]-based complexes (M¼Rh, Ir) propelled these half-sandwich organometallic complexes to the forefront of modern homogeneous organometallic catalysis. Indeed, an immense number of catalytic transformations initiated by the formation, via C–H activation, of the metallacyclic intermediates have been reported, enabling straightforward and waste- and step-economic synthesis of various compounds, mainly heterocyclic scaffolds.

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